Supramolecular energy materials also hold great potential in the design of systems for photovoltaics in which intermolecular interactions in self-assembled structures, for example, in electron donor and acceptor phases, maximize charge transport and avoid exciton recombination. Possible pathways to integrate organic and inorganic …
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Photosynthetic organisms harness solar radiation to produce energy-rich compounds from water and atmospheric CO<sub>2</sub> via exquisite supramolecular assemblies, which offers a design principle for highly efficient artificial photocatalytic systems. As an emerging research field, significant effort has been devoted to self-assembled supramolecular …
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Supramolecular materials have the merits of diverse functional groups, flexible structure, and unique self-healing properties, which make them of great value in the field of energy …
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Supramolecular functional materials represent an emerging class of materials that have been governed by the supramolecular chemistry of self-assembled molecules. Such high-order …
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2.1.2. Heteroatom doping of carbon-based materials Heteroatom doping has been shown to be an effective way for enhancing the electrochemical activity of carbon-based materials. 78,79 Among these heteroatoms, …
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Supramolecular gels comprise low-molecular weight gelators that assemble by non-covalent interactions. In this Review, a range of fabrication methods, as well as strategies for shaping ...
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1 Introduction The multitude of compositions and structures of 2D layered materials render promise for next-generation energy storage, [] thermoelectric, [] catalytic, [] and memory devices. [] Recently, atomically laminated ceramics, known as MAX phases, [] have garnered increased attention due to the discovery of so-called MXenes. [] ...
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The preparation of ordered mesoporous materials has been summarized. . Methods to control pore size and morphology of mesoporous materials are reviewed. . Mesoporous materials are used as electrocatalyst support and ultracapacitors. Designing new energy storage system is necessary for renewable energy development.
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supramolecular-derived materials for supercapacitors is prospected. 1. Introduction Supercapacitors have gained much attention in the last two decades as a new type of energy storage device. The energy density of supercapacitors is 3–4 times higher than that of
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Provides an overview of the structure, properties, and functions of nanocarbons. Focuses on an array of energy applications, including fuel cells and Li-ion batteries and supercapacitors. Offers a valuable resource for academics and industrial scientists alike. Part of the book series: Nanostructure Science and Technology (NST)
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These materials are formed from the ordered aggregation of molecules through noncovalent bonds to yield extended supramolecular materials that would contain catalytic units []. These systems may combine …
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Materials and Molecular Design. Materials and Molecular Design research involves the development and optimisation of molecules and advanced materials for a wide range of applications including pharmaceuticals, catalysts, self-healing, advanced electronics, biomaterials, electrical insulation, nanocomposites, energy storage and generation.
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3 Application of Ti 3 C 2 T x MXenes in energy storage and conversion 2D materials have attracted extensive attention due to their controllable interfacial chemistry [], high electronic conductivity, high optical transparency [65, 66], and tunable layered structure, which make 2D Ti 3 C 2 T x MXenes a promising electrode material in energy storage devices [15, …
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Synthetic systems to capture and store the Sun''s energy can be based on a light-harvesting moiety coupled to a redox-active catalyst to make chemical bonds — such as H2 from 2H+ and 2e− ...
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A detailed discussion on the rheological aspect of gel is crucial for the construction of soft materials. Generally, LMWGs are solid-like, although they are formed with very low gelator concentrations (George and Weiss 2006) and are potentially used in a wide range of areas, including sensing, energy storage, catalysis, drug delivery, optoelectronics, tissue …
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Supramolecular catalysis is hallmarked by the ability of host molecules to stabilize encapsulated reactive species through a number of non-covalent …
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Supramolecular materials are of course created with molecules, but the design of their components is based on specific noncovalent interactions across scales, including hydrogen bonds, π–π stacking, metal–ligand interactions, electrostatics, dipolar interactions, and steric forces, among others. Molecular design then programs the ...
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Elemental two-dimensional (2D) materials have emerged as promising candidates for energy and catalysis applications due to their unique physical, chemical, and electronic properties. These materials are advantageous in offering massive surface-to-volume ratios, favorable transport properties, intriguing physicochemical properties, and …
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The supramolecular self-assembly of lipopeptides is highly dependent on the nature of the hydrophobic tail, the sequence of amino acids and external stimuli, defining their applications in the ...
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The U.S. Department of Energy''s Office of Scientific and Technical Information @article{osti_1822875, title = {Supramolecular Energy Materials}, author = {Dumele, Oliver and Chen, Jiahao and Passarelli, James V. and Stupp, Samuel I.}, abstractNote = {Abstract Self‐assembly is a bioinspired strategy to craft materials for …
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Pillararene: A New, Strong Performer in Macrocyclic Supramolecular Chemistry Supramolecular chemistry, which aims to manipulate organic/inorganic entities to become ordered assemblies with higher complexity via non-covalent interactions such as hydrogen bonding, π–π interactions, C–H···π interactions, electrostatic interactions, …
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energy hopping in such materials.26 Similar results were achieved in a bi-component system using charge-transfer interactions between naphthalene and 1,2,4,5-tetracyanobenzene to assemble rigid tubes.
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combine the advantages of organic/inorganic, polymeric, and supramolecular materials. Consequently, M−MCOFs hold great potential in energy storage, adsorption, separation, sensing, catalysis, etc. This review focuses on the concepts with a ...
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After the discovery of graphene, molybdenum disulfide (MoS 2) has become the most studied material in the TMDs family due to its structural similarity to graphene.Due to its high carrier transport, low cost, and tunable bandgap, MoS 2 has been explored in various applications such as energy storage and conversion, photocatalysis, and …
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The Energy Storage, Harvesting and Catalysis group conducts cutting edge research in emergent technologies to facilitate the energy transition: from materials to reactors of disruptive electrochemical and chemical energy storage devices contributing to the society descarbonization by reducing CO2 emissions or reusing CO2.
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Organic electrodes are attractive candidates for electrochemical energy storage devices because they are lightweight, inexpensive and environmentally friendly. In recent years, many researchers have focused …
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materials17–19, self-assembly of supramolecular complexes (for example, phenolic resins with block ... for supercapacitive energy storage and cathode host materials for lithium–sulphur (Li–S ...
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One of the long-term objectives of the field described here as supramolecular energy materials is to learn how to design soft materials containing …
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The ability to incorporate specific functions in a precise manner makes POPs promising platforms for a myriad of applications in molecular adsorption, separation, and catalysis. Therefore, many different types of POPs have been rationally designed and synthesized to expand the scope of advanced materials, endowing them with distinct …
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